| # | Team Name | Captain | Vice Captain |
|---|---|---|---|
| 1 | Brimingham Phoenix Women
(100 2021 - Domestic) |
Amy Jones  |
|
| 2 | Brimingham Phoenix Women
(2024 Test League) |
Amy Jones |
|
| 3 | Manchester Originals Women
(100 2021 - Domestic) |
Kate Cross | |
| 4 | Manchester Originals Women
(2024 Test League) |
Kate Cross | |
| 5 | Northern Superchargers Women
(100 2021 - Domestic) |
||
| 6 | Northern Superchargers Women
(2024 Test League) |
||
| 7 | Oval Invincibles Women
(100 2021 - Domestic) |
||
| 8 | Oval Invincibles Women
(2024 Test League) |
||
| 9 | Southern Brave Women
(100 2021 - Domestic) |
Anya Shrubsole | |
| 10 | Southern Brave Women
(2024 Test League) |
Anya Shrubsole | |
| 11 | Trent Rockets Women
(100 2021 - Domestic) |
Nat Sciver | |
| 12 | Trent Rockets Women
(2024 Test League) |
Nat Sciver | |
| 13 | Welsh Fire Women
(100 2021 - Domestic) |
Sophie Luff |
|
| 14 | Welsh Fire Women
(2024 Test League) |
Sophie Luff |
